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Recent Advances in the Use of Black TiO2 for Production of Hydrogen and Other Solar Fuels

Chatzitakis, Athanasios Eleftherios; Sartori, Sabrina
Journal article; AcceptedVersion; Peer reviewed
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Minireview_Black+TiO2_Chatzitakis_Sartori.pdf (1.160Mb)
Year
2019
Permanent link
http://urn.nb.no/URN:NBN:no-80563

CRIStin
1677247

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Appears in the following Collection
  • Kjemisk institutt [825]
  • Institutt for teknologisystemer [66]
  • Det matematisk-naturvitenskapelige fakultet [246]
  • CRIStin høstingsarkiv [15033]
Original version
ChemPhysChem. 2019, 20 (10), 1272-1281, DOI: https://doi.org/10.1002/cphc.201801094
Abstract
Black TiO2 has emerged as one of the most promising photocatalysts recently discovered. The reason behind its catalytic activity is considered to be due to the presence of defects and Ti3+ species at the surface of black TiO2 nanostructures, which are crucial for its diverse applications. Moreover, disordered/crystalline surface layers and bulk regions have been identified and appear to influence the intrinsic properties of the material. Here, we present the latest studies on the use of black TiO2 for metal free hydrogen production, as well as for CO2 photoreduction and N2 photofixation. After highlighting the structure/property relations, we conclude with some critical questions and suggest further topics of research in order to better understand the underlying mechanisms of light absorption in black TiO2, especially towards solar fuels production.
 
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