dc.date.accessioned | 2020-05-27T18:23:14Z | |
dc.date.available | 2021-03-23T23:45:46Z | |
dc.date.created | 2019-07-17T10:45:57Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Bugaev, Aram L. Skorynina, Alina A. Braglia, Luca Lomachenko, Kirill A. Guda, Alexander Lazzarini, Andrea Bordiga, Silvia Olsbye, Unni Lillerud, Karl Petter Soldatov, Alexander V. Lamberti, Carlo . Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks. Catalysis Today. 2019, 336, 33-39 | |
dc.identifier.uri | http://hdl.handle.net/10852/76328 | |
dc.description.abstract | Functionalization of metal-organic frameworks (MOFs) with noble metals is a promising way for producing new versatile catalysts that will combine the outstanding porosity and specific surface area of MOFs with high catalytic activity of metals. Here, we present a comparative study of two metal-organic frameworks with UiO-67 topology, functionalized with palladium and platinum moieties. The initial structure of all studied samples contained palladium or platinum atoms grafted into MCl2bpydc (M = Pd, Pt) linkers of MOFs. The materials were further activated by heating in inert and H2-containing atmospheres. Both Pd- and Pt- functionalized materials exhibited high thermal stability upon heating in these atmospheres. The evolution of Pt and Pd species during the activation procedure was monitored by in situ time-resolved X-ray absorption near-edge structure (XANES) spectroscopy. We applied multivariate curve resolution alternating least squares (MCR-ALS) approach to XANES to unravel the intermediates which can be formed during the activation procedure. For UiO-67-Pd, only simple one-step transformation from PdCl2bpydc to Pd nanoparticles (NPs) was observed. For UiO-67-Pt, two additional intermediate states were observed, which behave differently depending on the activation procedure. Theoretical calculation of XANES spectra allowed us to suggest the 3D-atomic structures corresponding to each of the pure spectra determined by MCR-ALS. In addition, reaction enthalpies for different possible reaction routes were calculated within a density functional theory approach. Based on the experimental and theoretical results showed that Pd nanoparticles (NPs) tend to be formed in UiO-67-Pd samples irrespective of the activation procedure, while either Pt NPs or isolated PtII active sites, grafted in the MOF framework may be formed in UiO-67-Pt samples depending on the activation temperature and atmosphere. | |
dc.language | EN | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.title | Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks | |
dc.type | Journal article | |
dc.creator.author | Bugaev, Aram L. | |
dc.creator.author | Skorynina, Alina A. | |
dc.creator.author | Braglia, Luca | |
dc.creator.author | Lomachenko, Kirill A. | |
dc.creator.author | Guda, Alexander | |
dc.creator.author | Lazzarini, Andrea | |
dc.creator.author | Bordiga, Silvia | |
dc.creator.author | Olsbye, Unni | |
dc.creator.author | Lillerud, Karl Petter | |
dc.creator.author | Soldatov, Alexander V. | |
dc.creator.author | Lamberti, Carlo | |
cristin.unitcode | 185,15,12,0 | |
cristin.unitname | Kjemisk institutt | |
cristin.ispublished | true | |
cristin.fulltext | postprint | |
cristin.qualitycode | 2 | |
dc.identifier.cristin | 1711749 | |
dc.identifier.bibliographiccitation | info:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Catalysis Today&rft.volume=336&rft.spage=33&rft.date=2019 | |
dc.identifier.jtitle | Catalysis Today | |
dc.identifier.volume | 336 | |
dc.identifier.startpage | 33 | |
dc.identifier.endpage | 39 | |
dc.identifier.doi | https://doi.org/10.1016/j.cattod.2019.03.054 | |
dc.identifier.urn | URN:NBN:no-79447 | |
dc.type.document | Tidsskriftartikkel | |
dc.type.peerreviewed | Peer reviewed | |
dc.source.issn | 0920-5861 | |
dc.identifier.fulltext | Fulltext https://www.duo.uio.no/bitstream/handle/10852/76328/2/Bugaev_CATTOD_2018_1039_Revision.pdf | |
dc.type.version | AcceptedVersion | |
dc.relation.project | NFR/250795 | |