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dc.date.accessioned2020-11-04T19:50:20Z
dc.date.available2020-11-04T19:50:20Z
dc.date.created2020-10-16T12:50:10Z
dc.date.issued2020
dc.identifier.citationHylland, Knut Tormodssønn Øien-Ødegaard, Sigurd Heyn, Richard H. Tilset, Mats . Zinc schiff base complexes derived from 2,2'-diaminobiphenyls: Solution behavior and reactivity towards nitrogen bases. European Journal of Inorganic Chemistry (EurJIC). 2020, 38, 3627-3643
dc.identifier.urihttp://hdl.handle.net/10852/80862
dc.description.abstractZn complexes of Schiff base ligands derived from 2,2'‐diaminobiphenyls and salicylaldehyde derivatives were synthesized and characterized by NMR and single‐crystal X‐ray diffraction analysis. The detailed NMR studies suggest that the Zn complexes have a complicated behavior in solution, which is strongly dependent on the donating ability of the solvent, the steric properties of the ligand, as well as the concentration of the complex in the solvent. All these factors are decisive for the determination of the coordination number of the complex in solution. Furthermore, pentacoordinated Zn complexes of the aforementioned type, ligated by a series of nitrogen bases, were synthesized. NMR studies of the different complexes at different concentrations and temperatures, revealed information about their conformational stability. The differences were further examined by single‐crystal X‐ray diffraction analysis. In addition to the studies conducted on Zn complexes, comparative studies were conducted on a series of Cd complexes.
dc.languageEN
dc.rightsAttribution 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.titleZinc schiff base complexes derived from 2,2'-diaminobiphenyls: Solution behavior and reactivity towards nitrogen bases
dc.typeJournal article
dc.creator.authorHylland, Knut Tormodssønn
dc.creator.authorØien-Ødegaard, Sigurd
dc.creator.authorHeyn, Richard H.
dc.creator.authorTilset, Mats
cristin.unitcode185,15,12,0
cristin.unitnameKjemisk institutt
cristin.ispublishedtrue
cristin.fulltextoriginal
cristin.qualitycode1
dc.identifier.cristin1840138
dc.identifier.bibliographiccitationinfo:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European Journal of Inorganic Chemistry (EurJIC)&rft.volume=38&rft.spage=3627&rft.date=2020
dc.identifier.jtitleEuropean Journal of Inorganic Chemistry (EurJIC)
dc.identifier.volume38
dc.identifier.startpage3627
dc.identifier.endpage3643
dc.identifier.doihttps://doi.org/10.1002/ejic.202000589
dc.identifier.urnURN:NBN:no-83936
dc.type.documentTidsskriftartikkel
dc.type.peerreviewedPeer reviewed
dc.source.issn1434-1948
dc.identifier.fulltextFulltext https://www.duo.uio.no/bitstream/handle/10852/80862/1/Hylland%2Bet.al.%2B2020.pdf
dc.type.versionPublishedVersion
dc.relation.projectNFR/228157


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