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Development of Cu-based electrodes for proton-conducting membrane reactors

Robinson, Shay Alexander
Doctoral thesis
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PhD-Robinson-2017.pdf (13.09Mb)
Year
2017
Permanent link
http://urn.nb.no/URN:NBN:no-70735

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  • Kjemisk institutt [843]
Abstract
This dissertation is submitted in partial fulfilment of the requirements for the degree of Philosophiae Doctor (PhD) at Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Oslo, Norway. The work has been carried out at the Centre for Materials Science and Nanotechnology (SMN) in the Group for Solid State Electrochemistry under the supervision of Professor Truls Norby during the period of June 1st, 2013 to August 8th, 2017.
List of papers
Manuscript I: Comparison of Cu and Pt point-contact electrodes on proton conducting BaZr0.7Ce0.2Y0.1O3−δ. Shay Robinson, Christian Kjølseth, Truls Norby. Solid State Ionics, 306 (2017), 38-47. DOI: 10.1016/j.ssi.2017.02.014. The article is included in the thesis. Also available at: https://doi.org/10.1016/j.ssi.2017.02.014
Manuscript II: Thermally stable Cu-Co electrodes, with and without CeO2 surface activation, on a BaZr0:7Ce0:2Y0:1O3−δ proton conducting electrolyte. Shay Robinson, Christian Kjølseth, Truls Norby. To be published. The paper is not available in DUO awaiting publishing.
Manuscript III: Performance of a co-sintered backbone infiltrated with Cu-Co and CeO2 on a BaZr0:7Ce0:2Y0:1O−δ proton conducting electrolyte. Shay Robinson, Christian Kjølseth, Truls Norby. To be published. The paper is not available in DUO awaiting publishing.
Manuscript IV: Performance of a Cu-Co-CeO2 infiltrated backbone electrode on a BaZr0:7Ce0:2Y0:1O3−δ proton conducting electrolyte. Shay Robinson, Christian Kjølseth, Truls Norby. To be published. The paper is not available in DUO awaiting publishing.
Manuscript V: Galvanic hydrogen pumping in the protonic ceramic perovskite BaZr0:7Ce0:2Y0:1O3−δ. Shay Robinson, Anthony Manerbino, W. Grover Coors. Journal of Membrane Science, 446, 99-105, 2013. DOI: 10.1016/j.memsci.2013.06.026. The article is included in the thesis. Also available at: https://doi.org/10.1016/j.memsci.2013.06.026
Manuscript VI: Ba0.5Gd0.8La0.7Co2O6-δ infiltrated in porous BaZr0.7Ce0.2Y0.1O3 backbones as electrode material for proton ceramic electrolytes. Ragnar Strandbakke, Einar V øllestad, Shay Robinson, Marie-Laure Fontaine, Truls Norby. Journal of the Electrochemical Society, 164 (4) F196-F202 (2017). DOI: 10.1149/2.0141704jes. The paper is not available in DUO due to publisher restrictions. The published version is available at: https://doi.org/10.1149/2.0141704jes
 
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