The assembly of Gondwana in the Ediacaran was concluded by extensive arc magmatism along its northern margin. Extensional events in the early Paleozoic led to rifting and the eventual separation of terranes, which were later assimilated in different continents and orogens. The Sibak area of northeastern Iran records these events, including late Precambrian volcanic-sedimentary processes, metamorphism, and magmatism. A granite at Chahak in the Sibak Complex yields a zircon U–Pb age of 548.3 ± 1.1 Ma, whereas a spatially associated gabbro has an age of 471.1 ± 0.9 Ma. The latter corresponds to the earliest stages of rifting in the nearby Alborz domain, with the deposition of clastic sedimentary sequences, basaltic volcanism, and, as indicated by indirect evidence, coeval granitic plutonism. The Chahak gabbro is thus one of the earliest witnesses of the rifting processes that eventually led to the development of the Rheic Ocean and were indirectly linked to subduction of Iapetus at the Laurentian margin and the early development of the Appalachian orogen.