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Synthesis of 8-hydroxyphenanthridines employing Intramolecular Diels-Alder of Furan as the key step

Serigstad, Halvard
Master thesis
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Master-thesis---Halvard-Serigstad.pdf (3.510Mb)
Year
2018
Permanent link
http://urn.nb.no/URN:NBN:no-64374

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  • Kjemisk institutt [843]
Abstract
Abstract A synthetic strategy towards 8-hydroxyphenanthridines (6) was previously developed in our group, where intramolecular Diels-Alder of furan (IMDAF) was the key step. This was a continuation of a previous work as well. This strategy turned out to be not very efficient and a new and more robust strategy was planned out. The new strategy doesn’t involve diastereomers and is focused on obtaining 8- hydroxyphenanthridines in high yields, which later on can be explored for a fully functionalized ring c.
 
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