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Chemical Structures of Specific Sodium Ion Battery Components Determined by Operando Pair Distribution Function and X-ray Diffraction Computed Tomography

Sottmann, Jonas; Di Michiel, Marco; Fjellvåg, Helmer; Malavasi, Lorenzo; Margadonna, Serena; Vajeeston, Ponniah; Vaughan, Gavin B M; Wragg, David
Journal article; SubmittedVersion
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The+Intriguing+ ... osphorus+anodes5-1_mdm.pdf (1.859Mb)
Year
2017
Permanent link
http://urn.nb.no/URN:NBN:no-63380

CRIStin
1535947

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  • Kjemisk institutt [843]
  • CRIStin høstingsarkiv [15984]
Original version
Angewandte Chemie International Edition. 2017, 56 (38), 11385-11389, DOI: http://dx.doi.org/10.1002/anie.201704271
Abstract
To improve lithium and sodium ion battery technology, it is imperative to understand how the properties of the different components are controlled by their chemical structures. Operando structural studies give us some of the most useful information for understanding how batteries work, but it remains difficult to separate out the contributions of the various components of a battery stack (e.g., electrodes, current collectors, electrolyte, and binders) and examine specific materials. We have used operando X-ray diffraction computed tomography (XRD-CT) to study specific components of an essentially unmodified working cell and extract detailed, space-resolved structural information on both crystalline and amorphous phases that are present during cycling by Rietveld and pair distribution function (PDF) methods. We illustrate this method with the first detailed structural examination of the cycling of sodium in a phosphorus anode, revealing surprisingly different mechanisms for sodiation and desodiation in this promising, high-capacity anode system.

The final version of this research has been published in Angewandte Chemie International Edition. © 2017 Wiley
 
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