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C-C Bond formation in the purine 8-position by addition of allylmetals

Mai, Ngan Thi Kim
Master thesis
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Ngan_Mai_Master_Thesis.pdf (3.651Mb)
Year
2015
Permanent link
http://urn.nb.no/URN:NBN:no-49182

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  • Kjemisk institutt [845]
Abstract
8-Substituted purines have been extensively studied as for example anticancer or antiviral drugs. C-C Bond formation at the purine 8-position has been most commonly done via 8-halopurines, e.g. Pd-catalyzed coupling reactions. Meanwhile, direct conversion of purines not substituted at C-8 to 8-alkylpurines seems to be promising but there are few reports in the literature. In this thesis, addition of an allylmetallic reagent to 8-unsustituted purines followed by oxidation of the adduct to form 8-allylated purines will be discussed.
 
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