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dc.date.accessioned2015-08-05T12:11:50Z
dc.date.available2015-08-05T12:11:50Z
dc.date.created2015-04-14T18:03:14Z
dc.date.issued2015
dc.identifier.citationFilippova, Liudmila Stenstrøm, Yngve H. Hansen, Trond Vidar . Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C1-Symmetric Aminopinane-Derived Ligand. Molecules. 2015, 20, 6224-6236
dc.identifier.urihttp://hdl.handle.net/10852/44678
dc.description.abstractA novel C1-symmetric dinitrogen ligand was synthesized in high yield from commercially available (1R,2R,3R,5S)-(−)-isopinocampheylamine and 1-methyl-2- imidazolecarboxaldehyde. In combination with Cu(OAc)2∙H2O, this new ligand promote the reaction between nitromethane and aliphatic aldehydes with high yields (up to 97%) and moderate enantioselectivities (up to 67% ee). The reactions with benzaldehyde required prolonged reaction time that resulted in diminished yields, but accompanied with ee-values in the 55%–76% range.en_US
dc.languageEN
dc.language.isoenen_US
dc.rightsAttribution 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.titleCu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C1-Symmetric Aminopinane-Derived Liganden_US
dc.typeJournal articleen_US
dc.creator.authorFilippova, Liudmila
dc.creator.authorStenstrøm, Yngve H.
dc.creator.authorHansen, Trond Vidar
cristin.unitcode185,15,23,20
cristin.unitnameFarmasøytisk kjemi
cristin.ispublishedtrue
cristin.fulltextoriginal
cristin.qualitycode1
dc.identifier.cristin1237188
dc.identifier.bibliographiccitationinfo:ofi/fmt:kev:mtx:ctx&ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Molecules&rft.volume=20&rft.spage=6224&rft.date=2015
dc.identifier.jtitleMolecules
dc.identifier.volume20
dc.identifier.issue4
dc.identifier.startpage6224
dc.identifier.endpage6236
dc.identifier.doihttp://dx.doi.org/10.3390/molecules20046224
dc.identifier.urnURN:NBN:no-48954
dc.type.documentTidsskriftartikkelen_US
dc.type.peerreviewedPeer reviewed
dc.source.issn1420-3049
dc.identifier.fulltextFulltext https://www.duo.uio.no/bitstream/handle/10852/44678/2/molecules-20-06224.pdf
dc.type.versionPublishedVersion


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