Now showing items 1-16 of 16

  • Nielsen, Malte; Hafreager, Anders; Brogaard, Rasmus Yding; De Wispelaere, Kristof; Falsig, Hanne; Beato, Pablo; Van Speybroeck, Veronique; Svelle, Stian (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2019)
    When exposed to steam, zeolite catalysts are irreversibly deactivated by loss of acidity and framework degradation caused by dealumination. Steaming typically occurs at elevated temperatures, making it challenging to ...
  • Kvande, Karoline; Pappas, Dimitrios; Dyballa, Michael Martin; Buono, Carlo; Signorile, Matteo; Borfecchia, Elisa; Lomachenko, Kirill A.; Arstad, Bjørnar; Bordiga, Silvia; Berlier, Gloria; Olsbye, Unni; Beato, Pablo; Svelle, Stian (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2020)
    On our route towards a more sustainable future, the use of stranded and underutilized natural gas to produce chemicals would be a great aid in mitigating climate change, due to the reduced CO2 emissions in comparison to ...
  • Molino, Andrea; Lukaszuk, Katarzyna Anna; Rojo-Gama, Daniel; Lillerud, Karl Petter; Olsbye, Unni; Bordiga, Silvia; Svelle, Stian; Beato, Pablo (Journal article / Tidsskriftartikkel / SubmittedVersion, 2017)
    A variety of synthetic procedures have been used to obtain zeolite ZSM-23 (MTT) catalysts with crystallite sizes ranging from the micrometer to nanometer scale. When the acidic zeolite is used as catalyst for the Methanol ...
  • Borfecchia, Elisa; Beato, Pablo; Svelle, Stian; Olsbye, Unni; Lamberti, Carlo; Bordiga, Silvia (Journal article / Tidsskriftartikkel / SubmittedVersion, 2018)
    We review the structural chemistry and reactivity of copper-exchanged molecular sieves with chabazite (CHA) topology, as an industrially applied catalyst in ammonia mediated reduction of harmful nitrogen oxides (NH3-SCR) ...
  • Rojo-Gama, Daniel; Mentel, Lukasz; Kalantzopoulos, Georgios N.; Pappas, Dimitrios; Dovgaliuk, Iurii; Olsbye, Unni; Lillerud, Karl Petter; Beato, Pablo; Lundegaard, Lars Fahl; Wragg, David; Svelle, Stian (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2018)
    The deactivation of zeolite catalyst H-ZSM-5 by coking during the conversion of methanol to hydrocarbons was monitored by high-energy space- and time-resolved operando X-ray diffraction (XRD) . Space resolution was achieved ...
  • Zacharaki, Eirini; Beato, Pablo; Tiruvalam, Ramchandra R; Andersson, Klas J.; Fjellvåg, Helmer; Sjåstad, Anja Olafsen (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2017)
    In the past few decades, advances in colloidal nanoparticle synthesis have created new possibilities for the preparation of supported model catalysts. However, effective removal of surfactants is a prerequisite to evaluate ...
  • Pinilla-Herrero, Irene; Borfecchia, Elisa; Holzinger, Julian; Mentzel, Uffe V.; Joensen, Finn; Lomachenko, Kirill A.; Bordiga, Silvia; Lamberti, Carlo; Berlier, Gloria; Olsbye, Unni; Svelle, Stian; Skibsted, Jørgen; Beato, Pablo (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2018)
    Two series of Zn-ZSM-5 catalysts were prepared by ion exchanging two commercial zeolites with different Si/Al ratios (40 and 15) with increasing Zn loadings. The nature of the Zn sites in the zeolite was studied by ...
  • Del Campo, Pablo; Olsbye, Unni; Lillerud, Karl Petter; Svelle, Stian; Beato, Pablo (Journal article / Tidsskriftartikkel / SubmittedVersion, 2018)
    In the present study, a series of H-ZSM-22 mesoporous catalysts resulting from three different desilication treatments (NaOH treatment, treatment using mixtures of NaOH/CTAB and using mixtures of NaOH/TBAOH) and sequential ...
  • Pappas, Dimitrios; Borfecchia, Elisa; Dyballa, Michael Martin; Pankin, Ilia A.; Lomachenko, Kirill A.; Martini, Andrea; Signorile, Matteo; Teketel, Shewangizaw; Arstad, Bjørnar; Berlier, Gloria; Lamberti, Carlo; Bordiga, Silvia; Olsbye, Unni; Lillerud, Karl Petter; Svelle, Stian; Beato, Pablo (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2017)
    Cu-exchanged zeolites possess active sites that are able to cleave the C–H bond of methane at temperatures ≤200 °C, enabling its selective partial oxidation to methanol. Herein we explore this process over Cu-SSZ-13 ...
  • Teketel, Shewangizaw; Lundegaard, Lars Fahl; Skistad, Wegard; Chavan, Sachin Maruti; Olsbye, Unni; Lillerud, Karl Petter; Beato, Pablo; Svelle, Stian (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2015)
    Zeolites are crystalline aluminosilicates that are widely used as shape-selective catalysts in the refinery and petrochemical industries. By synthesizing a series of structurally related zeolite catalyst and applying them ...
  • Rojo-Gama, Daniel; Nielsen, Malte; Wragg, David; Dyballa, Michael Martin; Holzinger, Julian; Falsig, Hanne; Lundegaard, Lars Fahl; Beato, Pablo; Brogaard, Rasmus Yding; Lillerud, Karl Petter; Olsbye, Unni; Svelle, Stian (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2017)
    ZSM-5 is a widely used zeolite catalyst and is employed industrially for the methanol to gasoline (MTG) process. Even so, deactivation of ZSM-5 by coke formation constitutes a major technical and also fundamental challenge. ...
  • Rojo-Gama, Daniel; Signorile, Matteo; Bonino, Francesca; Bordiga, Silvia; Olsbye, Unni; Lillerud, Karl Petter; Beato, Pablo; Svelle, Stian (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2017)
    Catalyst deactivation during the methanol-to-hydrocarbons (MTH) reaction was investigated using five different commercially prepared microporous catalysts, including Mordenite, ZSM-22, ZSM-5, zeolite Beta and SAPO-34. The ...
  • Molino, Andrea; Holzinger, J.; Lukaszuk, Katarzyna Anna; Rojo-Gama, Daniel; Gunnæs, Anette Eleonora; Skibsted, J.; Lundegaard, Lars Fahl; Svelle, Stian; Beato, Pablo; Bordiga, Silvia; Lillerud, Karl Petter (Journal article / Tidsskriftartikkel / SubmittedVersion, 2019)
    A series of zeolite ZSM-23 samples prepared with different organic structure-directing agents, gave rise to crystalline phases, which show a large variety of particle dimensions. A detailed analysis of the structure of ...
  • Signorile, Matteo; Rojo-Gama, Daniel; Bonino, Francesca; Beato, Pablo; Svelle, Stian; Bordiga, Silvia (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2018)
    The methanol-to-hydrocarbons (MTH) reaction represents a versatile, industrially viable alternative to crude-oil based processes for the production of chemicals and fuels. In the MTH reaction, the shape selectivity of ...
  • Lukaszuk, Katarzyna Anna; Rojo-Gama, Daniel; Øien-Ødegaard, Sigurd; Lazzarini, Andrea; Berlier, Gloria; Bordiga, Silvia; Lillerud, Karl Petter; Olsbye, Unni; Beato, Pablo; Lundegaard, Lars Fahl; Svelle, Stian (Journal article / Tidsskriftartikkel / AcceptedVersion; Peer reviewed, 2017)
    The synthesis, characterization and catalytic performance of offretite with four distinct crystal morphologies (oval, hexagonal, broccoli-like, and spherical) are presented. As a member of the ABC-6 family of zeolite ...
  • Dyballa, Michael Martin; Thorshaug, Knut; Pappas, Dimitrios; Borfecchia, Elisa; Kvande, Karoline; Bordiga, Silvia; Berlier, Gloria; Lazzarini, Andrea; Olsbye, Unni; Beato, Pablo; Svelle, Stian; Arstad, Bjørnar (Journal article / Tidsskriftartikkel / PublishedVersion; Peer reviewed, 2019)
    This contribution clarifies the overoxidation-preventing key step in the methane-to-methanol (MTM) conversion over copper mordenite zeolites. We followed the methane-to-methanol conversion over copper mordenite zeolites ...